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| Registros recuperados: 28 | |
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| Limberger,Renata Pereira; Aleixo,Adriana Mendes; Fett-Neto,Arthur Germano; Henriques,Amélia T. |
| This work describes the bioconversion of (-)- and (+)-alpha-pinene (2,6,6-trimethyl-bicyclo[3.1.1]hept-2-ene), targeted at the production of (-)- and (+)-verbenone (4,6,6-trimethyl-bicyclo (3.1.1) hept-3-en-2-one), respectively, using Psychotria brachyceras and Rauvolfia sellowii cell suspension cultures. P. brachyceras showed selectivity to (-)-alpha-pinene with 80.9% conversion (relative integrated area gas chromatography-mass spectrometry (GC-MS)) of (-)-verbenone in 10-day-incubation, whereas R. sellowii was able to convert both pinene enantiomers (37.6% conversion of (-)-verbenone in 7-day-incubation and 32.2% conversion of (+)-verbenone in 10-day-incubation). In both systems trans-verbenol was formed as main product and then slowly biocatalyzed to... |
| Tipo: Journal article |
Palavras-chave: Alpha-pinene; Biotransformation; Verbenol; Verbenone. |
| Ano: 2007 |
URL: http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-34582007000400003 |
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| Ito,Felicia Megumi; Mena,Ana Elisa Maciel; Marques,Maria Rita; Lima,Dênis Pires de; Beatriz,Adilson. |
| The present study aimed to evaluate the ability for biotransformation of the Diels-Alder adduct tricyclo[6.2.1.0(2,7)]undeca-4,9-dien-3,6-dione (1) and two synthetic derivatives by the saprobe fungus Mucor ramosissimus Samutsevitsch. Products from oxidation, isomerization and, regioselective and enantioselective reduction were achieved. |
| Tipo: Info:eu-repo/semantics/article |
Palavras-chave: Mucor ramosissimus; Biotransformation; Diels-Alder adduct. |
| Ano: 2009 |
URL: http://www.scielo.br/scielo.php?script=sci_arttext&pid=S1517-83822009000300019 |
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| Behrens, Daphne; Rouxel, Julien; Burgeot, Thierry; Akcha, Farida. |
| Herbicides are one of the major classes of pollutants contaminating coastal waters over the world. Among them, diuron (3-(3,4-dichlorophenyl)-1,1-dimethylurea) is a phenylurea herbicide frequently detected in oyster-producing area, known to be toxic for this important exploited non-target species. With the aim to investigate the mechanisms by which diuron displays its toxicity in oyster, the implication of both biotransformation and oxygen reactive species (ROS) production was studied considering embryotoxicity and genotoxicity as endpoints. Comparative embryotoxicity and genotoxicity of diuron and its main metabolites (DCPMU, DCPU and 3,4-DCA) were thus studied on oyster larvae by the embryo-larval bioassay on D larvae and the comet assay on trochophore... |
| Tipo: Text |
Palavras-chave: Oyster; Herbicide; Embryotoxicity; Genotoxicity; Oxidative stress; Biotransformation. |
| Ano: 2016 |
URL: http://archimer.ifremer.fr/doc/00324/43521/43053.pdf |
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| Bodin, Nathalie. |
| Marine decapod crustaceans are macrobenthic opportunist species, of great commercial interest, and can accumulate pollutants. Worrying about consumers' safety, polychlorobiphenyls (PCBs), polybromodiphenyl Ethers (PBDEs) and dioxins (PCDD/Fs) were analyzed in four crustacean species from the coastal waters of Brittany and Normandy. As regards to regulations, the consumption of crustacean muscle doesn't raise any health problems. The second objective of this study was to evaluate the biological processes influencing PCB bioaccumulation in the spider crab Maja brachydactyla. From a quantitative point of view, organotropism, diet and age were the major factors acting on contamination. From a qualitative point of view, PCB fingerprints depended on sex, and to... |
| Tipo: Text |
Palavras-chave: Food safety; Biotransformation; Biomagnification; Food webs; Stable isotopes; Decapod crustaceans; Bioaccumulation; Polychlorinated biphenyls; Organic contaminants; Sécurité sanitaire; Biotransformation; Bioamplification; Réseaux trophiques; Isotopes stables; Crustacés décapodes; Bioaccumulation; Contaminants organiques. |
| Ano: 2005 |
URL: http://archimer.ifremer.fr/doc/2005/these-1149.pdf |
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| Mercimek,Hatice Aysun; Dincer,Sadik; Guzeldag,Gulcihan; Ozsavli,Aysenur; Matyar,Fatih; Arkut,Afet; Kayis,Fikret; Ozdenefe,Melis Sumengen. |
| Degradation of 2,4,6-trinitrotoluene (TNT), a nitroaromatic explosive found in the soil and ground water, was investigated using Pseudomonas aeruginosa in in vitroexperiments. Biodegradable abilitiy of this bacteria was performed with 50 and 75 mg L−1 TNT concentrations in a defined liquid medium for 96 h time period. Treatment of TNT in supernatant samples taken at 0, 6, 12, 24, 48, 72 and 96 h from agitated vessels was followed by reverse-phase high-performance liquid chromatography (HPLC). In cultures supplemented with 50 and 75 mgL−1 TNT, after 96 h of incubation 46% and 59% reduction were detected respectively. Two metabolites as degradation intermediates with nitrite release into the medium, 2,4-dinitrotoluene (2,4-DNT) and 4-aminodinitrotoluene... |
| Tipo: Info:eu-repo/semantics/article |
Palavras-chave: Pseudomonas sp; Biotransformation; Nitroaromatic explosives; TNT. |
| Ano: 2015 |
URL: http://www.scielo.br/scielo.php?script=sci_arttext&pid=S1517-83822015000100103 |
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| Munschy, Catherine; Moisan, Karine; Tixier, Celine; Olivier, Nathalie; Gastineau, Olivier; Le Bayon, Nicolas; Buchet, Vincent. |
| The uptake and elimination of six PBDE congeners (BDE-28, -47, -99, -100, -153, -209) were studied in juvenile common sole (Solea solea L) exposed to spiked contaminated food over a three-month period, then depurated over a five-month period. The results show that all of the studied PBDEs accumulate in fish tissues, including the higher brominated congener BDE-209. Several additional PBDE congeners were identified in the tissues of exposed fish, revealing PBDE transformation, mainly via debromination. The identified congeners originating from PBDE debromination include BDE-49 and BDE-202 and a series of unidentified tetra-, penta-, and hepta- BDEs. Contaminant assimilation efficiencies (AEs) were related to their hydrophobicity (log K-ow) and influenced by... |
| Tipo: Text |
Palavras-chave: Marine flatfish; PBDEs; Bioaccumulation; Biotransformation; Debromination. |
| Ano: 2011 |
URL: http://archimer.ifremer.fr/doc/00021/13188/11296.pdf |
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| Munschy, Catherine; Moisan, Karine; Tixier, Celine; Pacepavicius, G.; Alaee, M.. |
| The uptake, elimination and transformation of six PBDE congeners (BDE-28, -47, -99, -100, -153, -209) were studied in juvenile common sole (Solea solea L) exposed to spiked contaminated food over a three-month period, and then depurated over a five-month period. Methoxylated (MeO-) and hydroxylated (OH-) PBDEs were determined in fish plasma exposed to PBDEs and compared to those obtained in control fish. While all MeO- and some OH- congeners identified in fish plasma were found to originate from non-metabolic sources, several OH- congeners, i.e., OH-tetraBDEs and OH-pentaBDEs, were found to originate from fish metabolism. Among these, 4 '-OH-BDE-49 was identified as a BDE-47 metabolite. Congener 4 '-OH-BDE-101, identified here for the first time, may be... |
| Tipo: Text |
Palavras-chave: Marine flatfish; PBDEs; Bioaccumulation; Biotransformation; Hydroxylated metabolites. |
| Ano: 2010 |
URL: http://archimer.ifremer.fr/doc/00017/12811/11295.pdf |
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| Tian,Xun; Ye,Rui; Wang,Jingwen; Chen,Yifei; Cai,Baoguo; Guan,Shimin; Rong,Shaofeng; Li,Qianqian. |
| Background Natural 2-phenylethanol (2-PE) is an important flavoring that emits the aroma of roses. During biotransformation, the aroma quality of natural 2-PE is affected by its main by-products, which include butanol, isobutyric acid, butyric acid, and isovaleric acid. Thus, controlling undesirable by-product formation can reduce the effect of odor on 2-PE aroma quality. Results 2-PE was produced through biotransformation using l-phenylalanine as a substrate and glucose as a carbon source. Ascorbic acid was added to the system to improve the redox reaction and suppress the generation of by-products. Principal component analysis of the aroma quality of 2-PE was performed using an electronic nose. Similarity analysis revealed that the effects of four... |
| Tipo: Journal article |
Palavras-chave: Aroma quality; Ascorbic acid; Biotransformation; By-products; 2-Phenylethanol. |
| Ano: 2015 |
URL: http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-34582015000400005 |
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| Registros recuperados: 28 | |
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